2014年2月,石家庄指南针检测服务有限公司设立水质检测项目组。
检测的范围包括了生活污水,工业废水和生活饮用水。
一 生活污水
生产过程中排出的水,按工业废水中所含主要污染物的化学性质分为:含无机污染物为主的无机废水、含有机污染物为主的有机废水、兼含有机物和无机物的混合废水、重金属废水、含放射性物质的废水和仅受热污染的冷却水。例如电镀废水和矿物加工过程的废水是无机废水,食品或石油加工过程的废水是有机废水。按工业企业的产品和加工对象可分为:造纸废水、纺织废水、制革废水、农药废水、冶金废水、炼油废水等。按废水中所含污染物的主要成分可分为:酸性废水、碱性废水、含酚废水、含铬废水、含有机磷废水和放射性废水等。
二 生活饮用水
1.为防止介水传染病的发生和传播,要求生活饮用水不含病原微生物。
2.水中所含化学物质及放射性物质不得对人体健康产生危害,要求水中的化学物质及放射性物质不引起急性和慢性中毒及潜在的远期危害(致癌、致畸、致突变作用)。
3.水的感官性状是人们对饮用水的直观感觉,是评价水质的重要依据。生活饮用水必须确保感官良好,为人民所乐于饮用。
生活饮用水水质标准《生活饮用水卫生标准》(GB 5749-2006)共35项。其中感官性状和一般化学指标15项,主要为了保证饮用水的感官性状良好;毒理学指标15项、放射指标2项,是为了保证水质对人不产生毒性和潜在危害;细菌学指标3项是为了保证饮用水在流行病学上安全而制定的。我国现行的国家标准须检测项目共分五大指标106项。其中微生物指标6项、饮用水消毒剂4项、毒理指标74项、感官性状和一般理化指标20项、放射性指标2项。
三 检测指标
类别 |
检测项目 |
项目举例 |
水及水污染检测 |
现场检测 |
水温、pH、电导率、溶解氧、透明度、浊度等 |
理化项目 |
色度、悬浮物、可滤残渣、矿化度、氨氮、化学需氧量(CODcr)、高锰酸盐指数、生化需氧量(BOD5)、总氮、总磷、硝酸盐氮、亚硝酸盐氮、硫酸盐、阴离子表面活性剂、氟化物、氰化物等 |
|
重金属 |
汞、砷、镉、铅、铜、锌、铬、镍、钾、钠、钙、镁等 |
|
有机污染物 |
石油类、苯系物、氯苯类、硝基苯类、甲醛、甲醇、挥发性有机物、半挥发性有机物等 |
|
生物监测 |
有细菌总数、大肠菌群等 |
四 水质检测的指标的含义
1 菌落总数:在一定条件下(如需氧情况、营养条件、pH、培养温度和时间等)每克(每毫升)检样所生长出来的细菌菌落总数。按国家标准方法规定,即在需氧情况下,37℃培养48h,能在普通营养琼脂平板上生长的细菌菌落总数,所以厌氧或微需氧菌、有特殊营养要求的以及非嗜中温的细菌,由于现有条件不能满足其生理需求,故难以繁殖生长。因此菌落总数并不表示实际中的所有细菌总数,菌落总数并不能区分其中细菌的种类,所以有时被称为杂菌数,需氧菌数等。总大肠菌群:在饮用水的微生物安全监测中,普遍采用正常的肠道细菌作为粪便污染指标,而不是直接测定肠道致病菌。总大肠菌群系指一群需氧及兼性厌氧的,在37℃生长时能使乳糖发酵,在24h内产酸产气的革氏阴性无芽胞杆菌。总大肠菌群系指每升水样中所含有的总大肠菌群的数目。总大肠菌群可用多管发酵法或滤膜法检验。天鉴测试公正品质
2 游离氯:黄绿色气体。密度3.214克/升。熔点-100.98℃,沸点-34.6℃。化合价-1、+1、+3、+5和+7。有毒,剧烈窒息性臭味。电离能12.967电子伏特,具有强的氧化能力,能与有机物和无机物进行取代和加成反应;同许多金属和非金属能直接起反应。生活饮用水检测报价
三氯甲烷:无色透明液体。有特殊气味。味甜。高折光,不燃,质重,易挥发。纯品对光敏感,遇光照会与空气中的氧作用,逐渐分解而生成剧毒的光气(碳酰氯)和氯化氢。
3 溴酸盐:溴酸盐在国际上被定为2B级的潜在致癌物,它是矿泉水以及山泉水等多种天然水源在经过臭氧消毒后所生成的副产物。
氯酸盐:是氯酸所成的盐类,含有三角锥型的氯酸根离子—ClO3?,其中氯原子的氧化态为+5。氯酸盐有强氧化性,储存时应避免接触有机材料及还原性的物质。
4 色度:饮用水的色度如大于15度时多数人即可察觉,大于30度时人感到厌恶。标准中规定饮用水的色度不应超过15度。
5 浑浊度:为水样光学性质的一种表达语,用以表示水的清澈和浑浊的程度,是衡量水质良好程度的最重要指标之一,也是考核水处理设备净化效率和评价水处理技术状态的重要依据。浑浊度的降低就意味着水体中的有机物、细菌、病毒等微生物含量减少,这不仅可提高消毒杀菌效果,又利于降低卤化有机物的生成量。
6 臭和味:水臭的产生主要是有机物的存在,可能是生物活性增加的表现或工业污染所致。公共供水正常臭味的改变可能是原水水质改变或水处理不充分的信号。
7 余氯:余氯是指水经加氯消毒,接触一定时间后,余留在水中的氯量。在水中具有持续的杀菌能力可防止供水管道的自身污染,保证供水水质。
8 化学需氧量:是指化学氧化剂氧化水中有机污染物时所需氧量。化学耗氧量越高,表示水中有机污染物越多。水中有机污染物主要来源于生活污水或工业废水的排放、动植物腐烂分解后流入水体产生的。
9 细菌总数:水中含有的细菌,来源于空气、土壤、污水、垃圾和动植物的尸体,水中细菌的种类是多种多样的,其包括病原菌。
10 总大肠菌群:是一个粪便污染的指标菌,从中检出的情况可以表示水中有否粪便污染及其污染程度。在水的净化过程中,通过消毒处理后,总大肠菌群指数如能达到饮用水标准的要求,说明其他病原体原菌也基本被杀灭。标准是在检测中不超过3个/L。
11 耐热大肠菌群:它比大肠菌群更贴切地反应食品受人和动物粪便污染的程度,也是水体粪便污染的指示菌。
12 大肠埃希氏菌:大肠细菌(E. coli)为埃希氏菌属(Escherichia)代表菌。一般多不致病,为人和动物肠道中的常居菌,在一定条件下可引起肠道外感染。某些血清型菌株的致病性强,引起腹泻,统称病致病大肠杆菌。肠道杆菌是一群生物学性状相似的G-杆菌,多寄居于人和动物的肠道中。埃希菌属(Escherichia)是其中一类, 包括多种细菌,临床上以大肠埃希菌最为常见。大肠埃希菌(E.coli)通称大肠杆菌,是所有哺乳动物大肠中的正常寄生菌,一方面能合成维生素B及K供机体吸收利用。另一方面能抑制腐败菌及病原菌和真菌的过度增殖。但当它们离开肠道的寄生部位,进入到机体其他部位时,能引起感染发病。有些菌型有致病性,引起肠道或尿路感染性疾患。简而言之,大肠埃希菌=大肠杆菌 。
五 如何提高生活饮用水质量
1、购买品牌首选规模比较大的企业和知名品牌,饮用水已纳入质量安全市场准入管理,所有产品上应有QS标志。
2、看产品标签:合格的产品标签应清晰标注其产品名称、净含量、制造者名称、地址、生产日期、保质期、产品标准号等内容。
3、鉴别水的感官质量:合格的饮用水应该无色、透明、清澈、无异味、无异臭,没有肉眼可见物。颜色发黄、浑浊、有絮状沉淀或杂质,有异味的水一定不能饮用。
4、桶装、瓶装水一旦打开,应尽量在短期内使用完,不能久存。最好放在避光、通风阴凉的地方。
5、购买净水机制水时要看清机器的卫生状况,机器管理的巡视及滤芯更换及清洁频率记录。尽量选择机器的卫生状况良好,机器管理的巡视及滤芯更换及清洁频率高的购买。
六 关注二次供水
从水源地到水龙头,住宅小区的饮用水中间一般需历经四道关口,水源地、水厂、供水管网、二次供水,饮用水是否能够达标,不仅仅在于出厂水达标,更重要的是在供水末端合格。目前导致市区部分高层住户及地势较高区内的住户水压不足、用水困难的主要原因有三个:一是开发商在建房时未完善二次供水设施或物业公司没有正常使用二次供水设施;二是小区内或楼房内的用水管道铺设不合理,管径过小;三是使用已经淘汰的镀锌管或其它不合要求的非标管材等。而要解决上述问题,各住户应要求开发商或物业管理部门组织协调完善使用二次供水设施或铺设规范的供水管道。
蓄水池长期不清洗或消毒不彻底影响水质。饮用水是否能够达标,不仅仅在于出厂水达标,更重要的是在供水末梢合格。按不完全统计,目前市区有二次供水设施约8000多个,市自来水总公司专业清洗队每年清洗的蓄水池仅约2000个,还有一些请社会上的人员或自行清洗。由于部分使用单位对二次供水设施管理不重视,一些二次供水设施两三年甚至更长时间都不清洗,部分蓄水池蚊蝇滋生,甚至还有死鼠、死蛇等,造成水质污染。还有的二次供水设施仍在使用国家已明令禁止使用的铸铁管,这种管材经过长期使用后管道内壁容易结垢和锈蚀,影响小区住户的正常水压和水质安全,不符合国家生活饮用水卫生安全标准。
根据 《城市供水水质管理规定》(中华人民共和国建设部令第156号)第七条规定:“城市供水单位对其供应的水的质量负责,其中,经二次供水到达用户的,二次供水的水质由二次供水管理单位负责。”以及第十四条规定:“二次供水管理单位,应当建立水质管理制度,配备专(兼)职人员,加强水质管理,定期进行常规检测并对各类储水设施清洗消毒(每半年不得少于一次)。不具备相应水质检测能力的,应当委托经质量技术监督部门资质认定的水质检测机构进行现场检测。”此外也有规定,从事二次供水设施清洗消毒机构也必须有相关资质,需到相关部门备案。二次供水储水设施清洗消毒每半年不少于一次。二次供水设施清洗消毒服务首先要求清洗工作人员持有健康证,并按照相关清洗消毒操作规程进行清洗,消毒由专职人员实施,使用专用的清洗设备和工具。
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