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国家卫生计生委关于批准食品包装材料用添加剂新品种等的公告(2014年 第14号)
根据《中华人民共和国食品安全法》和《食品相关产品新品种行政许可管理规定》,现批准二氧化钛与正辛基三乙氧基硅烷的反应产物等10种物质为食品包装材料用添加剂新品种,2-丙烯酸与硅酸(H4SiO4)四甲酯的聚合物锌盐为食品包装材料用树脂新品种。批准2,2-二羟甲基丁醇食品包装材料用添加剂扩大使用范围。
  特此公告。
附件: 1. 食品包装材料用添加剂新品种
  2. 食品包装材料用树脂新品种
  3. 扩大使用范围的食品包装材料用添加剂
  国家卫生计生委
  2014年7月18日
  附件1
  食品包装材料用添加剂新品种
  一、  二氧化钛与正辛基三乙氧基硅烷的反应产物

产品名称 中文 二氧化钛与正辛基三乙氧基硅烷的反应产物
英文 Titanium dioxide reacted with octyltriethoxysilane
CAS号 ——
其他名称 正辛基三乙氧基硅烷改性二氧化钛Octyltriethoxysilane-modified titanium dioxide
使用范围 塑料、橡胶、粘合剂
最大使用量/% 25.0
特定迁移量或最大残留量/(mg/kg)
备注

二、氟修饰氧化铝表面处理的二氧化钛

产品名称 中文 氟修饰氧化铝表面处理的二氧化钛
英文 Titanium dioxide treated with fluoride modified alumina
CAS号 ——
使用范围 塑料、橡胶、粘合剂
最大使用量/% 25.0
特定迁移量或最大残留量/(mg/kg)
备注

三、α-[4-(3-丁氧基-2-氰基-3-氧代-1-丙烯基) -2-甲氧基苯基]-ω-羟基聚氧乙烯

产品名称 中文 α-[4-(3-丁氧基-2-氰基-3-氧代-1-丙烯基) -2-甲氧基苯基]-ω-羟基聚氧乙烯
英文 Poly(oxy-1,2-ethanediyl),α-[4-(3-butoxy-2-cyano-3-oxo-1-propenyl)-2-methoxyphenyl] -ω-hydroxy-
CAS号 780763-40-8
其他名称 丁基-2-氰基-3-(4-羟基-3-甲氧基)丙烯酸酯聚乙二醇醚Polyethyleneglycol ether of butyl 2-cyano-3-

(4-hydroxy-3-methoxyphenyl) acrylate

使用范围 塑料:PET
最大使用量/% 0.4
特定迁移量或最大残留量/(mg/kg)
备注 在所有温度条件下可接触水性、酸性和低酒精度(≤15%乙醇)食品;在100℃ 以下可接触油性和高酒精度(>15%乙醇)食品。

四、N,N’,N”-[(2,4,6-三氧代-1,3,5-三嗪-1, 3,5-(2H,4H,6H)-三基)三[亚甲基(3,5,5-三甲基-3,1-环己烷二基)]]-三[六氢化-2-氧代-1H-氮杂卓-1-甲酰胺]

产品名称 中文 N,N’,N”-[(2,4,6-三氧代-1,3,5-三嗪-1, 3,5-(2H,4H,6H)-三基)三[亚甲基(3,5,5-三甲基-3,1-环己烷二基)]]-三[六氢化-2-氧代-1H-氮杂卓-1-甲酰胺]
英文 1H-Azepine-1-carboxamide,N,N’,N”-[(2,4,6-trioxo-1,3,5-triazine-1,3,5(2H,4H,6H)-triyl)

tris[methylene(3,5,5-trimethyl-3,1-

cyclohexanediyl)]]tris[hexahydro-2-oxo-]

CAS号 68975-83-7
其他名称 己内酰胺封端的异佛尔酮二异氰酸酯三聚体
使用范围 涂料
最大使用量/% 按生产需要适量使用
特定迁移量或最大残留量/(mg/kg) 15.0(SML,以ε-己内酰胺计);1.0(QM,以异氰酸根计)
备注

五、2-甲基丙烯酸与环氧氯丙烷、苯乙烯和4,4′-(1-甲基亚乙基)双酚的聚合物

产品名称 中文 2-甲基丙烯酸与环氧氯丙烷、苯乙烯和4,4′-(1-甲基亚乙基)双酚的聚合物
英文 2-Propenoic acid,2-methyl-,polymer with(chloromethyl)oxirane,ethenylbenzene and

4,4′-(1-methylethylidene)bis[phenol]

CAS号 28262-39-7
其他名称 双酚A-表氯醇-甲基丙烯酸-苯乙烯共聚物;双酚A-环氧氯丙烷-甲基丙烯酸-苯乙烯共聚物
使用范围 涂料
最大使用量/% 按生产需要适量使用
特定迁移量或最大残留量/(mg/kg) 6.0(2甲基-2丙烯酸:SML)0.6(双酚A:SML)

1.0(环氧氯丙烷:QM)

备注

六、二磷酸与氧化四氟乙烯还原聚合物乙氧基化甲酯的聚合物

产品名称 中文 二磷酸与氧化四氟乙烯还原聚合物乙氧基化甲酯的聚合物
英文 Diphosphoric acid,polymers with ethoxylated Me esters of reduced polymd.oxidized tetrafluoroethylene
CAS号 200013-65-6
使用范围
最大使用量/% 1)非微波条件下: 1.52)微波条件下: 1.0
特定迁移量或最大残留量/(mg/kg) 1.5%(QM)0.24 mg/kg(环氧乙烷:QM)

1.6 mg/kg(1,4-二噁烷:QM)

备注

七、2,2,4-三甲基-1,3-戊二醇二异丁酸酯

产品名称 中文 2,2,4-三甲基-1,3-戊二醇二异丁酸酯
英文 2,2,4-trimethy1-1,3-pentanediol diisobutyrate
CAS号 6846-50-0
其他名称 TXIB
使用范围 塑料(PVC)、纸、粘合剂、油墨
最大使用量/% PVC:10.0纸、粘合剂、油墨:按生产需要适量使用
特定迁移量或最大残留量

/(mg/kg)

5.0(SML)
备注 用于塑料时,仅可用于重复使用的PVC制品(包括用于食品加工的PVC手套),使用温度不超过100℃。用于纸时,仅可接触干性食品。

八、碳化硅

产品名称 中文 碳化硅
英文 Silicon carbide
CAS号 409-21-2
使用范围 聚四氟乙烯涂料
最大使用量/% 15.0
特定迁移量或最大残留量/(mg/kg)
备注

九、溴化铵

产品名称 中文 溴化铵
英文 Ammonium bromide
CAS号 12124-97-9
使用范围
最大使用量/% 0.033(以纤维干重计)
特定迁移量或最大残留量/(mg/kg)
备注

十、2-丙烯酸丁酯与苯乙烯、2-甲基-2-丙烯酸、2-丙烯酸乙酯和2-甲基-2-丙烯酸环氧乙烷基甲基酯的聚合物

 产品名称 中文 2-丙烯酸丁酯与苯乙烯、2-甲基-2-丙烯酸、2-丙烯酸乙酯和2-甲基-2-丙烯酸环氧乙烷基甲基酯的聚合物
英文 2-Propenoic acid butyl ester, polymer with ethenyl benzene, 2-methyl-2-propenoic acid, 2-propenoic acid, ethyl ester, and 2-methyl-2-propenoic acid, oxiranylmethyl ester
CAS号 ——
其他名称 丙烯酸丁酯与苯乙烯、甲基丙烯酸、丙烯酸乙酯和甲基丙烯酸缩水甘油酯的聚合物
使用范围 涂料
最大使用量/% 按生产需要适量使用
特定迁移量或最大残留量

/(mg/kg)

6.0(丙烯酸丁酯:SML)6.0(2-甲基-2-丙烯酸:SML)

6.0(丙烯酸乙酯:SML)

0.02(2-甲基-2-丙烯酸环氧乙烷基甲基酯:SML)

备注 禁止用于接触婴幼儿食品。

附件2:食品包装材料用树脂新品种

产品名称 中文 2-丙烯酸与硅酸(H4SiO4)四甲酯的聚合物锌盐
英文 2-Propenoic acid, polymer with silicic acid (H4SiO4) tetramethyl ester, zinc salt
CAS号 1338452-06-4
其他名称 聚丙烯酸-硅氧化物交联树脂
通用类别名 PAA
特定迁移量或最大残留量/(mg/kg) 6.0(2-丙烯酸:SML);25.0(锌:SML)
备注 与食品间需由聚丙烯(厚度不低于30μm)或线型低密度聚乙烯(厚度不低于50μm)或其他具有相同或更好阻隔性能的已批准使用的聚合物分隔。

附件3:扩大使用范围的食品包装材料用添加剂

产品名称 中文 2,2-二羟甲基丁醇
英文 2,2-bis(hydroxymethyl)-1-butanol
CAS号 77-99-6
其他名称 3-羟甲基丙烷;Trimethylolpropane;TMP
扩大的使用范围 塑料、油墨
最大使用量/% 0.12
特定迁移量或最大残留量

/(mg/kg)

6.0(SML)
备注

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